Femtosecond real-time probing of reactions. IX. Hydrogen-atom transfer

The real-time dynamics of hydrogen-atom-transfer processes under collisionless conditions are studied using femtosecond depletion techniques. The experiments focus on the methyl salicylate system, which exhibits ultrafast hydrogen motion between two oxygen atoms due to molecular tautomerization, loosely referred to as intramolecular ''proton'' transfer. To test for tunneling and mass effects on the excited potential surface, we also studied deuterium and methyl-group substitutions. We observe that the motion of the hydrogen, under collisionless conditions, takes place within 60 fs. At longer times, on the picosecond time scale, the hydrogen-transferred form decays with a threshold of 15.5 kJ/mol; this decay behavior was observed up to a total vibrational energy of approximately 7200 cm-1. The observed dynamics provide the global nature of the motion, which takes into account bonding before and after the motion, and the evolution of the wave packet from the initial nonequilibrium state to the transferred form along the O-H-O reaction coordinate. The vibrational periods (2pi/omega) of the relevant modes range from 13 fs (the OH stretch) to 190 fs (the low-frequency distortion) and the motion involves (in part) these coordinates. The intramolecular vibrational-energy redistribution dynamics at longer times are important to the hydrogen-bond dissociation and to the nonradiative decay of the hydrogen-transferred form

Universal Quantum Computation in a Neutral Atom Decoherence Free Subspace

In this paper, we propose a way to achieve protected universal computation in a neutral atom quantum computer subject to collective dephasing. Our proposal relies on the existence of a Decoherence Free Subspace (DFS), resulting from symmetry properties of the errors. After briefly describing the physical system and the error model considered, we show how to encode information into the DFS and build a complete set of safe universal gates. Finally, we provide numerical simulations for the fidelity of the different gates in the presence of time-dependent phase errors and discuss their performance and practical feasibility.Comment: 7 pages, 8 figure

Adiabatic Elimination in a Lambda System

This paper deals with different ways to extract the effective two-dimensional lower level dynamics of a lambda system excited by off-resonant laser beams. We present a commonly used procedure for elimination of the upper level, and we show that it may lead to ambiguous results. To overcome this problem and better understand the applicability conditions of this scheme, we review two rigorous methods which allow us both to derive an unambiguous effective two-level Hamiltonian of the system and to quantify the accuracy of the approximation achieved: the first one relies on the exact solution of the Schrodinger equation, while the second one resorts to the Green's function formalism and the Feshbach projection operator technique.Comment: 14 pages, 3 figure

Error correction in ensemble registers for quantum repeaters and quantum computers

We propose to use a collective excitation blockade mechanism to identify errors that occur due to disturbances of single atoms in ensemble quantum registers where qubits are stored in the collective population of different internal atomic states. A simple error correction procedure and a simple decoherence-free encoding of ensemble qubits in the hyperfine states of alkali atoms are presented.Comment: 4 pages, 2 figure

Tur\'an Graphs, Stability Number, and Fibonacci Index

The Fibonacci index of a graph is the number of its stable sets. This parameter is widely studied and has applications in chemical graph theory. In this paper, we establish tight upper bounds for the Fibonacci index in terms of the stability number and the order of general graphs and connected graphs. Tur\'an graphs frequently appear in extremal graph theory. We show that Tur\'an graphs and a connected variant of them are also extremal for these particular problems.Comment: 11 pages, 3 figure

ISO far-infrared observations of rich galaxy clusters II. Sersic 159-03

The far-infrared emission from rich galaxy clusters is investigated. Maps have been obtained by ISO at 60, 100, 135, and 200 microns using the PHT-C camera. Ground based imaging and spectroscopy were also acquired. Here we present the results for the cooling flow cluster Sersic 159-03. An infrared source coincident with the dominant cD galaxy is found. Some off-center sources are also present, but without any obvious counterparts.Comment: 6 pages, 4 postscript figures, accepted for publication in `Astronomy and Astrophysics

Resveratrol given intraperitoneally does not inhibit the growth of high-risk t(4;11) acute lymphoblastic leukemia cells in a NOD/SCID mouse model.

The efficacy of resveratrol as a preventive agent against the growth of t(4;11) acute lymphoblastic leukemia (ALL) was evaluated in NOD.CB17-Prkdcscid/J mice engrafted with the human t(4;11) ALL SEM cell line. SEM cells were injected into the tail vein and engraftment was monitored by flow cytometry. Once engraftment was observed, mice were injected intraperitoneally with resveratrol (10 mg/kg body weight) dissolved in dimethylsulfoxide (DMSO) or DMSO alone (control) every other day, or vincristine (0.5 mg/kg body weight) 3 times per week for 4 weeks (n=16 per group). Comparisons of the percent of human leukemia cells in blood and survival curves showed resveratrol did not inhibit progression of the disease. Liquid chromatography-tandem mass spectrometry analyses of mouse sera showed resveratrol was rapidly metabolized to glucuronidated and sulfated forms 1 h post-injection, with low to no resveratrol or metabolites observed in sera by 24-48 h. These data indicate that in contrast to findings in in vitro models, parenterally administered resveratrol does not have potential as a preventive agent against high risk t(4;11) ALL

Correlation-induced conductance suppression at level degeneracy in a quantum dot

The large, level-dependent g-factors in an InSb nanowire quantum dot allow for the occurrence of a variety of level crossings in the dot. While we observe the standard conductance enhancement in the Coulomb blockade region for aligned levels with different spins due to the Kondo effect, a vanishing of the conductance is found at the alignment of levels with equal spins. This conductance suppression appears as a canyon cutting through the web of direct tunneling lines and an enclosed Coulomb blockade region. In the center of the Coulomb blockade region, we observe the predicted correlation-induced resonance, which now turns out to be part of a larger scenario. Our findings are supported by numerical and analytical calculations.Comment: 5 pages, 4 figure